HE–PIXE, Geant4, ARRONAX, Cu/Bi multilayer, HPGe detector, photon provenance, Monte Carlo modelling
AuthorsAbstractA Geant4 model was developed for the published ARRONAX high-energy particle-induced X-ray emission (HE–PIXE) benchmark using a 68 MeV pro-ton beam and a Cu/Bi multilayer target. The model combines low-energy electromagnetic transport, atomic relaxation, hadronic interactions, explicit air and detector-window attenuation, and an event-level photon-audit system that records the creator process, origin material and volume, exit layer, direction, energy, and statistical weight. The processed simulation was compared with a digitized experimental targetminus-background spectrum over the interval 5–90 keV. For the nor-malized spectral-shape comparison, the archived analysis output gave RMSE = 0.0610359, MAE = 0.0202528, Pearson correlation r = 0.625858, and R2 = 0.253298. These metrics quantify spectral-shape agreement only and do not estab-lish absolute X-ray yield because beam charge, acquisition live time, and a calibrated absolute detector efficiency were unavailable from the digitized benchmark. The audit contained 15,834 accepted photon records. The weighted creator-process contribution was dominated by hadron ionisation (74.5484%), followed by proton-inelastic production (11.0080%), electron ion-isation (7.2502%), and electron bremsstrahlung (6.3660%). The results demonstrate the diagnostic value of event-level photon provenance for identifying whether discrepancies originate from production physics, target geometry, attenuation, angular acceptance, or detectorresponse pro-cessing. The work therefore provides a transparent and reproducible frame-work for HE–PIXE model assessment while clearly separating normalized spectral-shape comparison from absolute experimental validation.
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